2024
(196)Ying Huang, Mingming Gao, Yubin Fu, Junke Li, Faxing Wang, Sheng Yang, Mingchao Wang, Zhengfang Qian*, Xing Lu*, Panpan Zhang*, Renheng Wang*: Hierarchical porous carbon nanofibers embedded with one-dimensional conjugated metal−organic framework anodes for ammonium-ion hybrid supercapacitors Energy Storage Materials 2024, 103522. DOI: 10.1016/j.ensm.2024.103522
(195)Ning Li, Mengyang Li, Kun Guo*, Ziqian Guo, Ruijie Wang, Lipiao Bao, Gao-Lei Hou*, Xing Lu*: Deciphering the Role of Native Defects in Dopant-Mediated Defect Engineering of Carbon Electrocatalysts Adv. Energy Mater. 2024, 2401008. DOI: 10.1002/aenm.202401008
(194)Feng Wang, Wangqiang Shen, Yuan Shui, Jun Chen, Huaiqiang Wang, Rui Wang, Yuyuan Qin, Xuefeng Wang, Jianguo Wan, Minhao Zhang*, Xing Lu*, Tao Yang* & Fengqi Song*:Electrically controlled nonvolatile switching of single-atom magnetism in a Dy@C84single-molecule transistor Nature Communications (2024) 15:2450. DOI:10.1038/s41467-024-46854-z
(193)Jiarun Chen, Mingjie Wang, Liuhua Chen, Kun Guo*, Boya Liu, Kai Wang, Ning Li, Lipiao Bao, and Xing Lu*:Intrinsic Defect-Rich Carbon-Supported Iron Phthalocyanine as Beyond-Pt Oxygen Reduction Catalysts for Zinc–Air Batteries Adv. Energy Sustainability Res. 2024, 2400010. DOI:10.1002/aesr.202400010
(192)Jun-Jie Fang, Zheng Liu, Zhi-Yi Wang, Yun-Peng Xie*, Xing Lu*:Chiral Canoe-like Pd0or Pt0Alloyed Copper Alkynyl Nanoclusters Display Near-infrared Luminescence Angew. Chem. Int. Ed. 2024, 63, e202401206. DOI:10.1002/anie.202401206
(191)Jun-Jie Fang, Zheng Liu, Yang-Lin Shen, Zhi-Yi Wang, Yun-Peng Xie*, Xing Lu*:Chiral Copper(I) Halide Clusters and Coordination Chain Exhibiting Photoluminescence and Circularly Polarized Luminescence ACS Materials Lett. 2024, 6, 4, 1199–1206. DOI:10.1021/acsmaterialslett.4c00290
(190)Mingming Gao, Faxing Wang, Sheng Yang, Antonio Gaetano Ricciardulli, Feng Yu, Junke Li, Jinhua Sun, Renheng Wang, Ying Huang*, Panpan Zhang*, Xing Lu*:Engineered 2D MXene-based materials for advanced supercapacitors and micro-supercapacitors Materials Today 2024, 72, 315-358. DOI:10.1016/j.mattod.2023.12.009
(189)Wangqiang Shen#, Chang Zhang#, Xinyu Wang#, Yuzhong Huang, Zhiling Du*, Muneerah Alomar, Junjie Wang, Jun Lv*, Jian Zhang*, and Xing Lu*：Sulfur-Doped Defective Nanocarbons Derived from Fullerenes as Electrocatalysts for Efficient and Selective H2O2Electroproduction ACS Materials Lett. 2024, 6, 1, 17-26. DOI:10.1021/acsmaterialslett.3c01036
(188)Chenli Huang, Ying Yang, Mengyang Li, Xiaoqun Qi, Changwang Pan, Kun Guo, Lipiao Bao*, Xing Lu*:Ultrahigh Capacity from Complexation-Enabled Aluminum-Ion Batteries with C70as the Cathode Adv. Mater. 2024, 36, 2306244. DOI:10.1002/adma.202306244
(187)Wanqiang Shen#, Chang Zhang#, Muneerah Alomar, Zhiling Du*, Zepeng yang, Junjie Wang, Guangqing Xu, Jian Zhang*, Jun Lv*, and Xing Lu*:Fullerene-derived boron-doped defective nanocarbon for highly selective H2O2electrosynthesis Nano Research 2024, 17(3): 1217−1224. DOI:10.1007/s12274-023-5999-x
(186)Kun Guo, Ning Li, Lipiao Bao*, Xing Lu*:Fullerenes and derivatives as electrocatalysts: Promises and challenges Green Energy & Environment, 9 (2024) 7-27. DOI:10.1016/j.gee.2022.11.002
2023
(185)Chenli Huang#, Rong Sun#, Lipiao Bao*, Xinyue Tian, Changwang Pan, Mengyang Li, Wangqiang Shen, Kun Guo, Bingwu Wang*, Xing Lu* & Song Gao:A hardmolecular nanomagnet from confined paramagnetic 3d-4f spins inside a fullerene cage Nature Communications (2023) 14:8443. DOI: 10.1038/s41467-023-44194-y
(184)Jun-Jie Fang, Zheng Liu, Yun-Peng Xie*, Xing Lu*:Superatomic Ag58nanoclusters incorporating a [MS4@Ag12]2+(M = Mo or W) kernel show aggregation-induced emission Chinese Chemical Letters 2023, 109345. DOI:10.1016/j.cclet.2023.109345
(183)Ning Li, Kun Guo*, Mengyang Li, Xiudi Shao, Zhiling Du, Lipiao Bao, Zhixin Yu, and Xing Lu*:Fullerene Fragment Restructuring: How Spatial Proximity Shapes Defect-Rich Carbon Electrocatalysts J. Am. Chem. Soc. 2023, 145, 45, 24580-24589. DOI:10.1021/jacs.3c06456
(182)Jun-Jie Fang, Zheng Liu, Yang-Lin Shen, Yun-Peng Xie*, and Xing Lu*:Template-Assisted Synthesis of Isomeric Copper(I) Clusters with Tunable Structures Show Photophysical and Electrochemical Properties Chem. Sci. 2023, 14, 12637-12644. DOI:10.1039/D3SC04682F
(181)Pengwei Yu#, Mengyang Li#, Shuaifeng Hu, Changwang Pan, Wangqiang Shen, Kun Guo, Yun-Peng Xie, Lipiao Bao*, Rui Zhang* and Xing Lu*:Stabilizing non-IPR C2(13333)-C74cage with Lu2C2/Lu2O: the importance of encaged non-metallic elements Chem. Commun. 2023, 59, 12990-12993. DOI:10.1039/D3CC04668K
(180)Mingming Gao, Zhiyong Wang, Zaichun Liu, Ying Huang, Faxing Wang, Mingchao Wang, Sheng Yang, Junke Li, Jinxin Liu, Haoyuan Qi, Panpan Zhang*, Xing Lu*, Xinliang Feng*:Two-Dimensional Conjugated Metal-Organic Frameworks Embedded with Iodine for High-Performance Ammonium-Ion Hybrid Supercapacitors Adv. Mater. 2023, 35, 2305575. DOI:10.1002/adma.202305575
(179)Kun Guo*, Zhimin He, Song Lu, Pengjun Zhang, Ning Li, Lipiao Bao, Zhixin Yu, Li Song, Xing Lu*：A Fullerene Seeded Strategy for Facile Construction of Nitrogen-Doped Carbon Nano-Onions as Robust Electrocatalysts Adv. Funct. Mater. 2023, 33, 2302100. DOI:10.1002/adfm.202302100
(178)Chang Zhang, Wangqiang Shen*, Kun Guo*, Mo Xiong, Jian Zhang*, and Xing Lu*：A Pentagonal Defect-Rich Metal-Free Carbon Electrocatalyst for Boosting Acidic O2 Reduction to H2O2Production J. Am. Chem. Soc. 2023, 145, 21, 11589-11598. DOI:10.1021/jacs.3c00689
(177)Pengwei Yu, Haocheng Mei, Shuaifeng Hu, Changwang Pan, Wangqiang Shen, Pengyuan Yu, Kun Guo, Yunpeng Xie, Takeshi Akasaka, Lipiao Bao* and Xing Lu*：Crystallographic Characterization of Lu2O@Cs(6)-C82and Er2O@Cs(6)-C82: The Role of Metal Species on Cluster Configuration Chin. J. Chem. 2023, 41, 1915-1920. DOI:10.1002/cjoc.202300019
(176)Kun Guo*, Ning Li, Lipiao Bao, Panpan Zhang*, Xing Lu*：Intrinsic carbon structural imperfections for enhancing energy conversion electrocatalysts Chemical Engineering Journal, 2023, 466, 143060. DOI:10.1016/j.cej.2023.143060
(175)Panpan Zhang, Mingchao Wang*, Yannan Liu, Yubin Fu, Mingming Gao, Gang Wang, Faxing Wang, Zhiyong Wang, Guangbo Chen, Sheng Yang, Youwen Liu, Renhao Dong, Minghao Yu*, Xing Lu, and Xinliang Feng*：Largely Pseudocapacitive Two-Dimensional Conjugated Metal–Organic Framework Anodes with Lowest Unoccupied Molecular Orbital Localized in Nickel-bis(dithiolene) Linkages J. Am. Chem. Soc. 2023, 145, 11, 6247-6256. DOI:10.1021/jacs.2c12684
(174)Ying Yang#, Chenli Huang#, Ruirui Zhao, Zhonghui Gao, Xiaoqun Qi, Wang Zhang, Xing Lu*, Long Qie* and Yunhui Huang*：Orbital hybridization states of carbon functionalize the alkali-ion storage capability of hard carbons Journal of Materials Chemistry A, 2023, 11, 2947-2956. DOI:10.1039/D2TA08691C
(173)Zhimin He#, Ziwei Zhou#, Peng Wei, Ting Xu, Jiantao Han, Keke Huang, Kun Guo*, Wenhuan Huang*, Takeshi Akasaka, and Xing Lu*：Fullerene-Derived Porous and Defective N-Doped Carbon Nanosheets as Advanced Trifunctional Metal-Free Electrocatalysts Chemistry-An Asian Journal, 2023, 18, e202200994. DOI：10.1002/asia.202200994
(172)Panpan Zhang#, Yang Li#, Mingming Gao, Sheng Yang, Mingchao Wang, Zaichun Liu, Kun Guo*, Faxing Wang*, Xing Lu*：Biomimetic platinum forest enables 3D micro-supercapacitors with enhanced areal performance Chemical Engineering Journal, 2023, 140357. DOI:10.1016/j.cej.2022.140357
2022
(171)Panpan Zhang, Sheng Yang, Honggui Xie, Yang Li, Faxing Wang, Mingming Gao, Kun Guo*, Renheng Wang*, and Xing Lu*：Advanced Three-Dimensional Microelectrode Architecture Design for High-Performance On-Chip Micro-Supercapacitors ACS Nano 2022, 16, 11, 17593–17612. DOI:10.1021/acsnano.2c07609
(170)Xin-Yan Xia, Yu-Han Xia, Jun-Jie Fang, Zheng Liu, Yun-Peng Xie*, and Xing Lu:Silver alkynyl coordination chains and clusters assembled with sulfonates Polyhedron, 2022, 116160. DOI:10.1016/j.poly.2022.116160
(169)Pengwei Yu, Shuaifeng Hu, Xinyue Tian, Wangqiang Shen, Pengyuan Yu, Kun Guo, Yunpeng Xie, Lipiao Bao* and Xing Lu*：Steering Lu3N cluster in C76-78 cages: Cluster configuration dominated by cage transformation Nanoscale 2022, 14, 17290-17296. DOI：10.1039/D2NR05049H
(168)Kun Guo, Litao Chang, Ning Li, Lipiao Bao, Samir de Moraes Shubeita, Aliaksandr Baidak, Zhixin Yu*, and Xing Lu*：Two Birds with One Stone: Concurrent Ligand Removal and Carbon Encapsulation Decipher Thickness-Dependent Catalytic Activity Nano Lett. 2022, 22, 21, 8763-8770. DOI:10.1021/acs.nanolett.2c03181
(167)Yu-Han Xia, Xin-Yan Xia, Jun-Jie Fang, Zheng Liu, Yun-Peng Xie*, and Xing Lu：Anion-templated silver thiolated clusters effected by carboxylate ligands Dalton Trans. 2022, 51, 14557-14562. DOI:10.1039/D2DT02194C
(166)Yu-Han Xia, Jun-Jie Fang, Xin-Yan Xia, Zheng Liu, Yun-Peng Xie*, and Xing Lu：Silver Clusters Coprotected by Different Diphosphine and Thiol Ligands Cryst. Growth Des. 2022, 22, 9, 5658-5665. DOI:10.1021/acs.cgd.2c00744
(165)Shuaifeng Hu, Pei Zhao*, Bo Li, Pengwei Yu, Le Yang, Masahiro Ehara, Peng Jin*, Takeshi Akasaka, and Xing Lu*：Cluster-Geometry-Associated Metal–Metal Bonding in Trimetallic Carbide Clusterfullerenes Inorg. Chem. 2022, 61, 29, 11277-11283. DOI:10.1021/acs.inorgchem.2c01399
(164)Ning Chen, Pengwei Yu, Kun Guo* and Xing Lu*:Rubrene-Directed Structural Transformation of Fullerene (C60) Microsheets to Nanorod Arrays with Enhanced Photoelectrochemical Properties Nanomaterials 2022, 12(6), 954. DOI:10.3390/nano12060954
(163)Pengju Li, Xiaobo Huang, Zhipeng Jiang, Han Zhang, Pengwei Yu， Xing Lu* and Jia Xie*:High-rate sodium metal batteries enabled by trifluormethylfullerene Nano Res. 2022, 15, 7172-7179. DOI:10.1007/s12274-022-4349-8
(162)Pengwei Yu+, Mengyang Li+, Wangqiang Shen, Shuaifeng Hu, Pengyuan Yu, Xinyue Tian, Xiang Zhao*, Lipiao Bao* and Xing Lu*：An unprecedented C80 cage that violates the isolated pentagon rule Inorg. Chem. Front. 2022, 9, 2264-2270. DOI:10.1039/D2QI00410K
(161)Lipiao Bao,Ting Xu,Kun Guo,Wenhuan Huang,Xing Lu*：Supramolecular Engineering of Crystalline Fullerene Micro-/Nano-Architectures Adv. Mater. 2022, 34, 2200189. DOI:10.1002/adma.202200189
(160)方俊杰, 刘铮, 谢云鹏*, 卢兴*：炔铜(I)纳米团簇的合成、结构规律与光电性质。科学通报, 2022. DOI:10.1360/TB-2021-1084
(159)Ting Xu, Hong Yin, Pengwei Yu, Zhimin He, Ning Chen, Wangqiang Shen, Mingqiang Zhu, Takeshi Akasaka, and Xing Lu*：Ultraviolet Photodetectors Based on Dimetallofullerene Lu2@Cs(6)-C82 Nanorods ACS Appl. Nano Mater. 2022, 5, 1, 1683-1689. DOI:10.1021/acsanm.1c04497
(158)Zhimin He, Peng Wei, Ting Xu, Ziqian Guo, Jiantao Han, Takeshi Akasaka, Kun Guo* and Xing Lu*：Defective porous carbon microrods derived from fullerenes (C70) as high-performance electrocatalysts for the oxygen reduction reaction Nanoscale 2022, 14, 473-481. DOI:10.1039/D1NR07198J
(157)Wangqiang Shen,Lipiao Bao,Xing Lu* ：Endohedral Metallofullerenes: An Ideal Platform of Sub-Nano Chemistry Chin. J. Chem. 2022, 40, 275-284. DOI:10.1002/cjoc.202100541
(156)Pengju Li, Yanglin Shen, Ximing Li, Wenhuan Huang*, Xing Lu*:Fullerene-Intercalated Graphitic Carbon Nitride as a High-Performance Anode Material for Sodium-Ion Batteries Energy & Environmental Materials 2022, 5, 608-616. DOI: 10.1002/eem2.12200
2021
(155)Xiaoqin Ye+, Pengwei Yu+, Wangqiang Shen*, Shuaifeng Hu, Takeshi Akasaka, Xing Lu*:Er@C82as a Bifunctional Additive to the Spiro-OMeTAD Hole Transport Layer for Improving Performance and Stability of Perovskite Solar Cells Sol. RRL 2021, 5, 2100463. DOI: 10.1002/solr.202100463
(154)Ning Chen, Yanglin Shen, Ting Xu, Wangqiang Shen, Xing Lu* :Morphology Engineering of Fullerene (C60) Microstructures Featuring Surface Cracks with Enhanced Photoluminescence and Microscopic Recognition Properties Chem. Eur. J. 2021, 27, 16212-16218. DOI: 10.1002/chem.202103123
(153)Zhimin He, Peng Wei, Ting Xu, Jiantao Han, Xuejiao Gao* and Xing Lu* ：Defect-rich N/S-Co-doped Porous Hollow Carbon Nanospheres Derived from Fullerenes as Efficient Electrocatalysts for Oxygen Reduction Reaction and Zn-air Batteries Mater. Chem. Front. 2021, 5, 7873-7882. DOI: 10.1039/D1QM00854D
(152)Jun-Jie Fang, Yang-Lin Shen, Zheng Liu, Chen Liu, Yun-Peng Xie,* and Xing Lu* :Copper(I) Alkynyl Clusters with Crystallization Induced Emission Enhancement Inorg. Chem. 2021, 60, 17, 13493–13499. DOI: 10.1021/acs.inorgchem.1c01829
(151)Pengju Li, Zhipeng Jiang, Xiaobo Huang, Xing Lu*, Jia Xie*, Shijie Cheng：Nitrofullerene as an Electrolyte-compatible Additive for High-performance Sodium Metal Batteries Nano Energy, Volume 89, Part A, November 2021, 106396. DOI: 10.1016/j.nanoen.2021.106396.
(150)Yang-Lin Shen+, Pei Zhao+, Junling Jin, Jun Han, Chen Liu, Zheng Liu, Masahiro Ehara, Yun-Peng Xie * and Xing Lu*:A Comparative Study of [Ag11(iPrS)9(dppb)3]2+and [Ag15S(sBuS)12(dppb)3]+: Templating effect on Structure and Photoluminescence Dalton Trans. 2021,50, 10561-10566. DOI: 10.1039/D1DT01111A
(149)Yajing Hu, Yang-Rong Yao, Xuechen Liu, Ao Yu, Xiaoming Xie, Laura Abella, Antonio Rodr´ıguez-Fortea, Josep M. Poblet, Takeshi Akasaka, Ping Peng, Qianyan Zhang,* Su-Yuan Xie, Fang-Fang Li * and Xing Lu *:Unexpected Formation of 1,2- and 1,4-Bismethoxyl Sc3N@Ih-C80Derivatives via Regioselective Anion Addition: Unambiguous Structural Identification and Mechanism Study Chem. Sci. 2021,12, 8123-8130. DOI: 10.1039/D1SC01178B
(148)Ting Xu, Ning Chen, Zhimin He, Pengwei Yu, Wangqiang Shen, Takeshi Akasaka, Xing Lu*:Morphology Engineering of Fullerene[C70] Microcrystals: From Perfect Cubes, Defective Hoppers to Novel Cruciform-Pillars Chem. Eur. J. 2021, 27, 10387–10393. DOI: 10.1002/chem.202100958
(147)Jingwei Xiang+, Wangqiang Shen+, Zezhou Guo, Jintao Meng, Lixia Yuan*, Yi Zhang, Zexiao Cheng, Yue Shen, Xing Lu*, Yunhui Huang*:A Supramolecular Complex of C60–S with High-Density Active Sites as a Cathode for Lithium–Sulfur Batteries Angew. Chem. Int. Ed. 2021, 60, 14313-14318. DOI: 10.1002/anie.202016247
(146)Yang-Lin Shen, Jun-Ling Jin, Jun-Jie Fang, Zheng Liu, Jian-Lin Shi, Yun-Peng Xie,* and Xing Lu*:Construction of Silver Clusters Capped by Zwitterionic Ethynide Ligands Inorg. Chem. 2021, 60, 9, 6276–6282. DOI: 10.1021/acs.inorgchem.0c03790
(145)Yang-Lin Shen, Jun-Ling Jin, Ning Chen, Peng Ju Li, Ting Xu, Yun-Peng Xie* and Xing Lu*:Controllable Synthesis of Porous Tubular Carbon with a Ag+-ligand Assisted Stöber-Silica/Carbon Assembly Process Nanoscale 2021,13, 2534-2541. DOI:10.1039/D0NR07785B
(144)Zhimin He, Peng Wei, Ning Chen, Jiantao Han and Xing Lu*:N,S-Codoped Porous Carbon Nanofiber Films Derived from Fullerenes (C60) as Efficient Electrocatalysts for Oxygen Reduction and Zn-Air Battery Chem. Eur.J. 2021, 27, 1423–1429. DOI: 10.1002/chem.202004535
(143)Xiaoqin Ye, Zhiyue Wen, Rui Zhang, Hanbing Ling, Jiangbin Xia* and Xing Lu*:High-performance and stable inverted perovskite solar cells using low-temperature solution-processed CuNbOxhole transport layer Journal of Power Sources 483 (2021) 229194. DOI: 10.1016/j.jpowsour.2020.229194
(142)Yang-Lin Shen, Jun-Ling Jin, Guang-Xiong Duan, Peng-Yuan Yu, Yun-Peng Xie* and Xing Lu*:Nest-Like Silver(I) Thiolate Clusters Templated by Hetero Anions with Tunable Colored Emission Chem. Eur.J. 2021, 27, 1122–112. DOI:10.1002/chem.202004055
(141)Nahar Jannatun, Ning Chen, Pengyuan Yu, Wangqiang Shen,*and Xing Lu*:Three-dimensional Cubic and Dice-like Microstructures of Higher Fullerene C78with Enhanced Photoelectrochemical and Photoluminescence Properties Chem. Eur. J. 2021, 27, 348–353. DOI: 10.1002/chem.202003476
2020
(140)Wangqiang Shen+, Le Yang+, Bo Li, Peng Jin*, Bing Yu*, Hailin Cong*, Takeshi Akasaka* and Xing Lu*:Metal-encapsulation induces a highly regioselective Bingel-Hirsch reaction of the labile Y@Cs(6)-C82 Chem. Commun.,2020, 56, 14357-14360. DOI: 10.1039/d0cc06226j
(139)Yang-Lin Shen, Jun-Ling Jin, Yun-Peng Xie,* and Xing Lu:tert-Butyl thiol and pyridine ligand co-protected 50-nuclei clusters: the effect of pyridines on Ag-SR bonds Dalton Trans. 2020, 49, 12574-12580. DOI: 10.1039/d0dt02003f
(138)Shen Yang-Lin, Jin Jun-Ling, Duan Guang-Xiong, Xie Yun-Peng,* and Lu Xing*:Formation of Spindle-Like Ag58Cluster Induced by Isomerization of [Ag14] Acta Chim. Sinica, 2020, 78, 1255-1259. DOI: 10.6023/A20070317
(137)Wangqiang shen+, Ziqi Hu+, Pengwei Yu+, Zhan Wei, Peng Jin*, Zujin Shi * and Xing Lu*:Experimental and Theoretical Study of LuNC@C76,82Revealing a Cage-cluster Selection Rule Inorg. Chem. Front. 2020, 7, 4563-4571. DOI: 10.1039/D0QI00781A
(136)Peng-Yuan Yu, Li-Piao Bao, Le-Yang, De-Bo Hao, Peng-Jin*, Wang-Qiang Shen*, Hong-Yun Fang*, Takeshi Akasaka, Xing Lu*:Crystallographic Characterization of Ti2C2@D3h(5)-C78, Ti2C2@C3v(8)-C82, and Ti2C2@Cs(6)-C82: Identification of Unsupported Ti2C2Cluster with Cage-Dependent Configurations Inorg. Chem. 2020, 59, 13, 9416-9423. DOI:10.1021/acs.inorgchem.0c01304
(135)Ning-Chen, Yi-Peng Hu, Ting-Xu, Xing Lu*:Three-Dimensional "Star of David"-Shaped Fullerene (C60) Microstructures: Controlled Synthesis, Photoluminescence, and Photoelectrochemical Properties ACS Appl. Electron. Mater. 2020, 2, 7, 2010-2016. DOI:10.1021/acsaelm.0c00290
(134)Ting-Xu, Dan-Yang Yu, Zhi-Ling Du, Wen-Huan Huang*, Xing Lu*:Two-Dimensional Mesoporous Carbon Materials Derived from Fullerene Microsheets for Energy Applications Chem. Eur.J. 2020, 26,10811–10816. DOI:10.1002/Chem.202001404
(133)Xiao-Qin Ye, Zhi-Yue Wen, Wang-Qiang Shen, Xing Lu*:Applications of fullerene materials in perovskite solar cells CIESC Journal, 2020, 71, 6, 2510-2529. DOI:10.11949/0438-1157.20200084
(132)Yun-Peng Xie,* Yang-Lin Shen, Guang-Xiong Duan, Jun Han, Lai-Ping Zhang, Xing Lu*:Silver Nanoclusters: Synthesis, Structures and Photoluminescence Mater. Chem. Front. 2020, 4, 2205-2222. DOI:10.1039/D0QM00117A
(131)Lan-Yun Li, Guang-Xiong Duan, Jing-Yan Liu, Lai-Ping Zhang, Yun-Peng Xie,* and Xing Lu:Heterometallic Cluster Coordination Polymers Assembled from Cuprous-Halide Clusters and Organotin-Oxygen Pyridinecarboxylate Clusters Cryst. Growth Des. 2020, 20, 6, 3795-3800. DOI:10.1021/acs.cgd.0c00077
(130)Ting Xu+, Wangqiang Shen+, Wenhuan Huang**, Xing Lu*:Fullerene Micro/Nanostructures: Controlled Synthesis and Energy Applications Materials Today Nano, 11(2020), 100081. DOI:10.1016/j.mtnano.2020.100081
(129)Wangqiang Shen, Lipiao Bao, Pengwei Yu, Le Yang, Bo Li, Pengyuan Yu, Peng Jin*, and Xing Lu*:Isolation and Crystallographic Characterization of Lu2C2@C2n(2n=88-92): Internal Cluster Stretching upon Outer Cage Expansion Carbon, 2020, 164, 157-163. DOI:10.1016/j.carbon.2020.03.062
(128)Shuaifeng Hu, Pei Zhao, Wangqiang Shen, Masahiro Ehara,* Yunpeng Xie,* Takeshi Akasaka,* and Xing Lu*:Crystallographic Characterization of Er2C2@C80–88: Cluster Stretching with Cage Elongation Inorg. Chem. 2020, 59, 3, 1940-1946. DOI: 10.1021/acs.inorgchem.9b03269
(127)Le Yang+, Wangqiang Shen+, Yangchun Liu, Debo Hao, Changwang Pan, Bing Yu,* Hailin Cong,* Peng Jin,* and Xing Lu*:Quantitative Mono-Formation and Crystallographic Characterization of Pyrazole- and Pyrrole-Ring Fused Derivatives of C60 Eur. J. Org. Chem. 2020, 2020, 12, 1866-1870. DOI: 10.1002/ejoc.202000138
(126)Wangqiang Shen+, Shuaifeng Hu+, and Xing Lu*:Endohedral Metallofullerenes: New Structures and Unseen Phenomena Chem. Eur. J. 2020, 26, 26, 5748-5757. DOI: 10.1002/chem.201905306
(125)Bing Yu, Wangqiang Shen, Le Yang, Yangchun Liu, Changwang Pan, Hailin Cong,* Peng Jin* and Xing Lu*:Regioselective Synthesis, Crystallographic Characterization and Electrochemical Properties of Pyrazole- and Pyrrole-ring Fused Derivatives of Y2@C3v(8)-C82 Chem. Eur. J. 2020, 26, 11, 2464-2469. DOI: 10.1002/chem.201905076
(124)Guangxiong Duan, Jun Han, Bao-Zhu Yang,* Yun-Peng Xie,* Xing Lu*:Oxometalate and Phosphine Ligands Co-protected Silver Nanoclusters: Ag28(dppb)6(MO4)4and Ag32(dppb)12(MO4)4(NO3)4 Nanoscale, 2020, 12, 1617-1622. DOI:10.1039/C9NR07779K
(123)Lipiao Bao, Ying Li, Pengyuan Yu, Wangqiang Shen, Peng Jin*, and Xing Lu*:Preferential formation of mono-metallofullerenes governed by the encapsulation energy of the metal elements: A case study on Eu@C2n(2n = 74-84) revealing a general rule Angew. Chem. Int. Ed. 2020, 59, 5259-5262. DOI: 10.1002/anie.201910743
(122)Xiaoqin Ye, Hanbing Ling, Rui Zhang, Zhiyue Wen, Shuaifeng Hu, Takeshi Akasaka, Jiangbin Xia,* Xing Lu,**:Low-temperature solution-combustion-processed Zn-Doped Nb2O5as an electron transport layer for efficient and stable perovskite solar cells Journal of Power Sources, 2020, 448, 227419. DOI: 10.1016/j.jpowsour.2019.227419
2019
(121)Pengyuan Yu+, Wangqiang Shen+, Lipiao Bao+, Changwang Pan, Zdenek Slanina and Xing Lu*:Trapping an unprecedented Ti3C3 unit into the icosahedral C80fullerene: A crystallographic survey Chem. Sci. 2019, 10, 10925-10930. DOI: 10.1039/C9SC04315B
(120)Yun-Peng Xie,* Jun-Bo Wen, Chang-Wang Pan, Guang-Xiong Duan, Lan-Yun Li, Xing Lu*:Assembly of Cu(I) Alkynyl Complexes: From Cluster to Infinite Cluster-Based Framework Crystal Growth & Design, 2019, 19, 10, 5791-5797. DOI: 10.1021/acs.cgd.9b00803
(119)Shuaifeng Hu+, Wangqiang Shen+, Pei Zhao+, Ting Xu, Zdenek Slanina, Masahiro Ehara, Xiang Zhao,* Yun-Peng Xie,* and Takeshi Akasaka,* Xing Lu*:Crystallographic Characterization of Er2C2@C2(43)-C90, Er2C2@C2(40)-C90, Er2C2@C2(44)-C90, and Er2C2@C1(21)-C90: The Role of Cage-Shape on Cluster Configuration Nanoscale, 2019, 11, 17319-17326. DOI: 10.1039/C9NR06466D
(118)Shuaifeng Hu, Wangqiang Shen, Le Yang, Guangxiong Duan, Peng Jin*, Yunpeng Xie*, Takeshi Akasaka*, and Xing Lu*:Crystallographic and Theoretical Investigations of Er2@C2n (2n = 82, 84, 86): Indication of Distance-Dependent Metal-Metal Bonding Nature Chem. Eur. J. 2019, 25, 11538-11544. DOI: 10.1002/chem.201902321
(117)Shuaifeng Hu, Pei Zhao, Wangqiang Shen, Pengyuan Yu, Wenhuan Huang*, Masahiro Ehara*, Yunpeng Xie*, Takeshi Akasaka*, and Xing Lu*:Crystallographic characterization of Er3N@C2n(2n = 80, 82, 84, 88): the importance of a planar Er3N cluster Nanoscale, 2019, 11, 13415-13422. DOI: 10.1039/c9nr04330f
(116)Lipiao Bao+, Bingzhe Wang+, Pengyuan Yu, Chenli Huang, Changwang Pan, Hongyun Fang*, Takeshi Akasaka*, Dirk M. Guldi*, and Xing Lu*:Intermolecular packing and charge transfer in metallofullerene/porphyrin cocrytals Chem. Commun. 2019, 55, 6018-6021. DOI: 10.1039/C9CC02095K
(115)Lipiao Bao, Pengyuan Yu, Ying Li, Changwang Pan, Wangqiang Shen, Peng Jin*, Shuquan Liang*, and Xing Lu*:Highly regioselective complexation of tungsten with Eu@C82/Eu@C84: interplay between endohedral and exohedral metallic units induced by electron transfer Chem. Sci. 2019, 10, 4945-4950. DOI: 10.1039/C9SC01479A
(114)Yunpeng Xie, Changwang Pan, Lipiao Bao, Zdenek Slanina, Takeshi Akasaka, and Xing Lu*:Regioselective Coordination of Re2(CO)10 to Y@C2v(9)-C82: An Unprecedented ¦Ç1 Complex Stabilized by Intramolecular Electron Transfer Organometallics, 2019, 38, 2259-2263. DOI: 10.1021/acs.organomet.9b00209
(113)Changwang Pan+, Wangqiang Shen+, Le Yang+, Lipiao Bao, Zhan Wei, Peng Jin*, Hongyun Fang*, Yunpeng Xie*, Takeshi Akasaka, and Xing Lu*:Crystallographic Characterization of Y2C2n(2n = 82, 88-94): Direct Y-Y Bonding and Cage-Dependent Cluster Evolution Chem. Sci. 2019, 10, 4707-4713. DOI: 10.1039/C9SC00941H
(112)Shuaifeng Hu, Tong Liu, Wangqiang Shen, Zdenek Slanina, Takeshi Akasaka*, Yunpeng Xie*, Filip Uhlik, Wenhuan Huang*, and Xing Lu*:Isolation and Structural Characterization of Er@C2v(9)-C82and Er@Cs(6)-C82: Regioselective Dimerization of a Pristine Endohedral Metallofullerene Induced by Cage Symmetry Inorg. Chem. 2019, 58, 3, 2177-2182. DOI: 10.1021/acs.inorgchem.8b03313
(111)Wangqiang Shen, Le Yang, Yongbo Wu, Lipiao Bao, Ying Li, Peng Jin*, Hongyun Fang*, Yunpeng Xie*, and Xing Lu*:Reactions between N-Heterocyclic Carbene and Lutetium-Metallofullerenes: High Regioselectivity Directed by Electronic Effect in Addition to Steric Hindrance J. Org. Chem. 2019, 84, 2, 606-612. DOI: 10.1021/acs.joc.8b02423
(110)Lipiao Bao, Pengyuan Yu, Changwang Pan, Wangqiang Shen, and Xing Lu*:Crystallographic identification of Eu@C2n (2n = 88, 86 and 84): completing a transformation map for existing metallofullerenes Chem. Sci. 2019, 10, 2153-2158. DOI: 10.1039/C8SC04906H
(109)Junling Jin, Yunpeng Xie*, and Xing Lu*:Hybrid Rare-Earth(III)/Bismuth(III) Clusters Assembled with Phosphonates Inorg. Chem. 2019, 58, 1, 648-654. DOI: 10.1021/acs.inorgchem.8b02811
(108)Wangqiang Shen, Lipiao Bao, Shuaifeng Hu, Le Yang, Peng Jin*, Yunpeng Xie*, Takeshi Akasaka, and Xing Lu*:Crystallographic Characterization of Lu2C2n (2n = 76-90): Cluster Selection by Cage Size Chem. Sci. 2019, 10, 829-836. DOI: 10.1039/C8SC03886D
2018
(107)Zhiling Du, Nahar Jannatun, Danyang Yu, Juan Ren, Wenhuan Huang*, and Xing Lu*:C60-decorated nickle-cobalt phosphide as an efficient and robust electrocatalyst for hydrogen evolution reaction Nanoscale, 2018,10, 23070-23079. DOI: 10.1039/C8NR07472K
(106)Wangqiang Shen, Lipiao Bao, Shuaifeng Hu, Xuejiao Gao*, Yunpeng Xie*, Xingfa Gao, Wenhuan Huang*, and Xing Lu*:Isolation and Crystallographic Characterization of Lu3N@C2n(2n=80-88): Cage Selection by Cluster Size Chem. Eur. J. 2018, 24, 16692-16698. DOI: 10.1002/chem.201804651
(105)Shushu Zheng, Nguyen Thanh Cuong, Susumu Okada, Ting Xu, Wangqiang Shen, Xing Lu* and Kazuhito Tsukagoshi*:Solvent-Mediated Shape Engineering of Fullerene (C60) Polyhedral Microcrystals Chem. Mater. 2018, 30, 20, 7146-7153. DOI: 10.1021/acs.chemmater.8b03095
(104)Guangxiong Duan, Lin Tian, Junbo Wen, Lanyun Li, Yunpeng Xie* and Xing Lu*:An Atomically Precise All-tert-Butylethynide-Protected Ag51 Superatom Nanocluster with Color Tunability Nanoscale, 2018, 10, 18915-18919. DOI:10.1039/C8NR06399K
(103)Junlin Jin, Yunpeng Xie* and Xing Lu*:High-nulearity silver ethynide clusters containing polynucleating oxygen donor ligands Dalton Trans. 2018, 47, 12972-12978. DOI: 10.1039/C8DT02700E
(102)Junling Jin, Yanglin Shen, Yunpeng Xie* and Xing Lu*:Anion Template Synthesis of Silver(I)-Ethynide Dithiophosphate Clusters Cryst. Growth Des. 2018, 18, 8, 4372-4377. DOI: 10.1021/acs.cgd.8b00308
(101)Yanbang Li,Ning Lou,Dan Xu, Changwang Pan,Xing Lu* and Liangbing Gan*:Oxygen-delivery Material: Synthesis of an Open-cage Fullerene Derivative Suitable for Encapsulation of H2O2and O2 Angew. Chem. Int. Ed. 2018, 57, 14144-14148. DOI: 10.1002/anie.201808926
(100)Guang-Xiong Duan,Yun-Peng Xie*,Jun-Ling Jin,Li-piao Bao, Xing Lu* and Thomas C. W. Mak:High-Nuclearity Heterometallic tert-Butylethynide ClustersAssembled with tert-Butylphosphonate Chem. Eur. J. 2018, 24, 1-8. DOI: 10.1002/chem.201705906
(99)Shushu Zheng,Junwen Zhong, Wakana Matsuda, Peng Jin, Muqing Chen, Takeshi Akasaka,Kazuhito Tsukagoshi*, Shu Seki*, Jun Zhou, Xing Lu*:Fullerene/cobaltporphyrin charge-transfer cocrystals: Excellent thermal stability and high mobility Nano Research, 2018, 11, 4, 1917-1927. DOI: 10.1007/s12274-017-1809-7
(98)JunLing Jin, YangLin Shen, YunPeng Xie* and Xing Lu*:Silver ethynide clusters constructed with fluorinated β-diketonate ligands CrystEngComm, 2018, 20, 2036-2042. DOI: 10.1039/C8CE00243F
(97)Lipiao Bao, Ping Peng, and Xing Lu*:Bonding inside and outside Fullerene Cages Acc. Chem. Res. 2018, 51, 3, 810-815. DOI: 10.1021/acs.accounts.8b00014
(96)Changwang Pan, Lipiao Bao, Xianyong Yu, Hongyun Fang, Yunpeng Xie, Takeshi Akasaka,and Xing Lu*:Facile Access to Y2C2n (2n = 92-130) and Crystallographic Characterization of Y2C2@C1(1660)-C108: A Giant Nanocapsule with a Linear Carbide Cluster ACS Nano 2018, 12, 2, 2065-2069. DOI: 10.1021/acsnano.8b00384
(95)Shushu Zheng, Xing Xiong, Zhi Zheng, Ting Xu, Li Zhang, Tianyou Zhai**, Xing Lu*:Solution-grown large-area C60single-crystal arrays as organic photodetectors Carbon, 2018, 126, 299-304. DOI: 10.1016/j.carbon.2017.10.012
2017
(94)Lipiao Bao+, Muqing Chen+, Wangqiang Shen, Le Yang, Peng Jin*, and Xing Lu*:Lewis Acid¨CBase Adducts of Sc2C2@C3v(8)-C82/N-Heterocyclic Carbene: Toward Isomerically Pure Metallofullerene Derivatives Inorg. Chem., 2017, 56, 24, 14747-14750. DOI: 10.1021/acs.inorgchem.7b0257
(93)Jun-Ling Jin, Yun-Peng Xie*, Han Cui, Guang-Xiong Duan, Xing Lu*, and Thomas C. W. Mak:Structure-Directing Role of Phosphonate in the Synthesis of High Nuclearity Silver(I) Sul?de-Ethynide-Thiolate Clusters Inorg. Chem., 2017, 56, 17, 10412-10417. DOI: 10.1021/acs.inorgchem.7b01326
(92)Wangqiang Shen+, Li Zhang+, Shushu Zheng, Yun-Peng Xie, and Xing Lu*:Lu2@C82 nanorods with enhanced photo-luminescence and photoelectrochemical properties ACS Appl. Mater. Interfaces, 2017, 9, 34, 28838-28843. DOI:10.1021/acsami.7b05180
(91)Bingzhe Wang+, Shushu Zheng+, Avishek Saha , Lipiao Bao, Xing Lu*, and Dirk M. Guldi* :Understanding Charge-Transfer Characteristics in Crystalline Nanosheets of Fullerene/(Metallo)porphyrin Cocrystals J. Am. Chem. Soc. 2017, 139, 30, 10578-10584. DOI: 10.1021/jacs.7b06162
(90)Wangqiang Shen, Lipiao Bao, Yongbo Wu, Changwang Pan, Shasha Zhao, Hongyun Fang, Yunpeng Xie, Peng Jin*, Ping Peng*, Fang-Fang Li*, and Xing Lu*:Lu2@C2n(2n= 82, 84, 86): Crystallographic Evidence of Direct Lu–Lu Bonding between Two Divalent Lutetium Ions Inside Fullerene Cages J. Am. Chem. Soc. 2017, 139, 29, 9979-9984. DOI: 10.1021/jacs.7b04421
(89)Muqing Chen+, Wangqiang Shen+, Ping Peng, Lipiao Bao, Shasha Zhao, Yunpeng Xie, Peng Jin*, Hongyun Fang*, Fang-Fang Li*, and Xing Lu*:Evidence of Oxygen Activation in the Reaction Between an N-heterocyclic Carbene and M3N@Ih(7)-C80 (M = Sc, Lu): An Unexpected Way of Steric Hindrance Release J. Org. Chem. 2017, 82, 7, 3500-3505. DOI: 10.1021/acs.joc.6b03004
(88)Shasha Zhao, Pei Zhao, Wenting Cai, Lipiao Bao, Muqing Chen, Yunpeng Xie, Xiang Zhao, Xing Lu*:Stabilization of Giant Fullerenes C2(41)-C90, D3(85)-C92, C1(132)-C94, C2(157)-C96, and C1(175)-C98 by Encapsulation of a Large La2C2 Cluster: The Importance of Cluster–Cage Matching J. Am. Chem. Soc. 2017, 139, 13, 4724-4728. DOI: 10.1021/jacs.6b11970
(87)Yun-Peng Xie*, Jun-Ling Jin, Guang-Xiong Duan, Xing Lu*, Thomas C.W. Mak*:High-nuclearity silver(I) chalcogenide clusters: A novel class of supramolecular assembly Coord. Chem. Rev. 2017, 331, 54-72. DOI: 10.1016/j.ccr.2016.10.007
(86)Avishek Saha, Muqing Chen, Marcus Lederer, Axel Kahnt, Xing Lu* and Dirk M. Guldi*:Sulfur rich electron donors - formation of singlet versus triplet radical ion pair states featuring different lifetimes in the same conjugate Chem. Sci. 2017, 8, 1360-1368. DOI: 10.1039/C6SC03207A
2016
(85)Chen, M.+; Bao, L.+; Peng, P.; Zheng, S.; Xie, Y.; Lu, X.*:Rigid Tether Directed Regioselective Synthesis and Crystallographic Characterization of Labile 1,2,3,4-Bis(triazolino)[60]fullerene and Its Thermolized Derivatives Angew. Chem. Int. Ed. 2016, 55, 11887-11891. DOI: 10.1002/anie.201606385
(84)Bao, L.; Pan, C.; Slanina, Z., Uhlik, F.; Akasaka, T.; Lu, X.*:Isolation and crystallographic characterization of the long-sought labile isomer of Y@C82cocrystallized with Ni(OEP): unprecedented dimerization of pristine metallofullerenes Angew. Chem. Int. Ed. 2016, 55, 9234-9238. DOI: 10. 1002/anie. 201604121
(83)Wei, T.; Wang, S.; Lu, X.; Tan, Y.; Huang, J.; Liu, F.; Li, Q.; Xie, S. Yang SF.*:Entrapping a Group-VB Transition Metal, Vanadium, within an Endohedral Metallofullerene: VxSc3-xN@Ih-C80 (x=1, 2) J. Am. Chem. Soc. 2016, 138, 207-214. DOI: 10.1021/jacs.5b10115
(82)Cai, W.; Li, F.; Bao, L.; Xie, Y.; Lu. X.*:Isolation and Crystallographic Characterization of La2C2@Cs(574)-C102 and La2C2@C2(816)-C104: Evidences for the Top-Down Formation Mechanism of Fullerenes J. Am. Chem. Soc. 2016, 138, 20, 6670-6675. DOI: 10.1021/jacs.6b03934
(81)Bao, L.; Chen, M.; Shen W.; Pan, C.; Ghlassl, B, K.; Olmstead, M, M.*; Balch, L, A.*; Akasaka, T.; Lu, X.*:Regioselective Synthesis and Crystallographic Characterization of Isoxazoline-Ring-Fused Derivatives of Sc3N@Ih-C80 and C60 Inorg. Chem. 2016, 55, 9, 4075-4077. DOI: 10.1021/acs.inorgchem.6b00631
(80)Bao, L.+; Liu, B.+; Li, X.; Pan, C.; Xie Y.; Lu, X.*:W(CO)3(Ph2PC2H4PPh2)(η2-Sc3N@Ih-C80/Sc3N@D5h-C80): regioselective synthesis and crystallographic characterization of air-stable mononuclear complexes of endohedral fullerenes Dalton Trans. 2016, 45 ,11606-11610. DOI: 10.1039/C6DT00790B
(79)Xu, G.; Deng, X.; Li, J.; Zhang, R.; Xie, Y-P.; Tu, G.; Xia, J.*; Lu, X.*:Lead Iodide as a New Type of Hole Transport Layer for High Performance of P3HT-PC61BM based Solar Cells Acta Phys.-Chim. Sin. 2016, 32, 6, 1307-1313. DOI: 10.3866/ PKU.WHXB201604083
(78)Huang, W.; Xu, J.*; Lu,X.*:Tapered carbon nanocone tips obtained by dynamic oxidation in air RSC Adv. 2016, 6, 25541-25548. DOI: 10.1039/c5ra25667d
(77)Bao, L.; Chen, M.; Pan, C.; Yamaguchi,T.; Kato,T.; Olmstead, M, M.; Balch, A, L.; Akasaka, T.; Lu, X.*:Crystallographic Evidence for Direct Metal-Metal Bonding in a Stable Open-Shell La2@Ih-C80 Derivative Angew. Chem. Int. Ed. 2016, 55, 4242-4246. DOI: 10.1002/anie. 201511930
(76)Chen, M.+; Bao, L.+; Ai, M.; Shen, W.; Lu, X.*:Sc3N@Ih-C80 as a Novel Lewis Acid to Trap Abnormal N-Heterocyclic Carbene: Unprecedented Formation of a Singly Bonded [6,6,6]-adduct Chem. Sci. 2016, 7, 2331-2334. DOI: 10.1039/C5SC04070A
2015
(75)Xie, Y.*; Jin, J.; Lu, X.*; Thomas, C.:High-Nuclearity/Silver Thiolate Clusters Constructed with Phosphonates Angew. Chem. Int. Ed. 2015, 54, 15176-15180. DOI: 10.1002/anie.201507512
(74)Zheng, S.; Xu, M.; Lu, X.*:Facile Method toward Hierarchical Fullerene Architectures with Enhanced Hydrophobicity and Photoluminescence ACS Appl. Mater. Interfaces. 2015, 7, 20285-20291. DOI: 10.1021/acsami.5b05869
(73)Cai, W.; Bao, L.; Zhao, S.; Xie, Y.; Akasaka, T.; Lu X.*:Anomalous Compression of D5(450)/C100 by Encapsulating La2C2 Cluster instead of La2 J. Am. Chem. Soc. 2015, 137, 10292-10296. DOI:10.1021/jacs.5b05668
(72)Shushu Zheng , Hui Ju , and Xing Lu *:A High/Performance Supercapacitor Based on KOH Activated 1D C70 Microstructures Adv. Ener. Mater. 2015, 5,1500871. DOI: 10.1002/aenm.201500871
(71)Muqing Chen+, Wangqiang Shen+, Lipiao Bao, Wenting Cai, Yunpeng Xie, Takeshi Akasaka, and Xing Lu*:Regioselective Thermal Reaction between Triethylamine and C60 Revisited: X/ray Confirmation of the Pentane/Fused Adduct and in Situ Mechanism Study Eur. J. Org. Chem. 2015, 5742-5746. DOI: 10.1002/ejoc.201500814
(70)Shushu Zheng and Xing Lu*:Formation kinetics and photoelectrochemical properties of crystalline C70 one/dimensional microstructures RSC Adv. 2015, 5, 38202-38208. DOI:10.1039/C5RA03678J
(69)Michio Yamada, Yasuhiro Muto, Hiroki Kurihara, Zdenek Slanina, Mitsuaki Suzuki, Yutaka Maeda, Yves Rubin,* Marilyn M. Olmstead,* Alan L. Balch,* Shigeru Nagase,* Xing Lu, and Takeshi Akasaka*:Regioselective Cage Opening of La2 @D2 (10611)C72 with 5,6-Diphenyl-3-(2-pyridyl)-1,2,4-triazine Angew. Chem. Int. Ed. 2015, 54, 2232-2235. DOI: 10.1002/anie.201410012
(68)Yamada, M.; Kurihara, H.; Suzuki, M.; Saito, M.; Slanina, Z.; Uhlik, F.; Aizawa, T.; Kato, T.; Olmstead, M. M.; Balch, A. L.; Maeda, Y.; Nagase, S.; Lu, X.; Akasaka, T.*:Hiding and recovering electrons in a dimetallic endohedral fullerene: air/stable products from radical additionsJ. Am. Chem. Soc., 2015, 137, 232-238. DOI:10.1002/anie.201410012
(67)Liu, B.; Fang, H.;Li, X.*; Cai, W.; Bao, L.; Rudolf, M.; Plass, F.; Fan, L.; Lu, X.*; Guldi, D. M.*:Synthesis and Photophysical Properties of a Sc3N@C80Corrole Electron Donor Acceptor Conjuga Chem. Eur. J. 2015, 21, 746-752. DOI: 10.1002/chem.201405572
(66)Feng, L.*; Rudolf, M.; Trukhina, O.; Slanina, Z.; Uhlik, F.; Lu, X.; Torres, T.*; Guldi, D. M.*; Akasaka, T.*:Tuning intramolecular electron and energy transfer processes in novel conjugates of La2@C80 and electron accepting subphthalocyanines Chem. Commun. 2015, 51, 330-333. DOI: 10.1039/c4cc08072f
(65)Cai, W.; Chen, M.; Bao, L.; Xie, Y.; Akasaka, T.*; Lu, X.*:In-Depth Understanding of the Chemical Properties of Rarely Explored Carbide Cluster Metallofullerenes: A Case Study of Sc2C2@C3v(8)C82 that Reveals a General Rule Chem. Eur. J. 2015, 21, 3449-3454. DOI: 10.1002/chem.201405493
2014
(64)Zhou, Q.; Li, H.; Lian, Y.*; Suzuki, M.; Bao, L.; Cai, W.; Wang, W.; Nagase, S.; Lu, X.; Akasaka, T.:Regioselective synthesis and molecular structure of the first derivative of praseodymium/containing metallofullerenes Chem. Commun. 2014, 50, 9876-9878. DOI: 10.1039/c4cc02949f
(63)Yamada, M.; Kurihara, H.; Suzuki, M.; Guo, J. D.; Waelchli, M.; Olmstead, M. M.; Balch, A. L.; Nagase, S.; Maeda, Y.; Hasegawa, T.; Lu, X.; Akasaka, T.*:Sc2@C66 Revisited: An Endohedral Fullerene with Scandium Ions Nestled within Two Unsaturated Linear Triquinanes J. Am. Chem. Soc. 2014, 136, 7611-7614. DOI: 10.1021/ja5035649
(62)Xiao, Y.; Zhu, S.E.; Liu, D.J.; Suzuki, M.; Lu, X.*; Wang, G.W.*:Regioselective Electrosynthesis of Rare 1,2,3,16/Functionalized 60 Fullerene Derivatives Angew. Chem. Int. Ed. 2014, 53, 3006-3010. DOI: 10.1002/anie.201310565
(61)Slanina, Z.*; Uhlik, F.; Lee, S.L.; Wang, B.C.; Adamowicz, L.; Suzuki, M.; Haranaka, M.; Feng, L.; Lu, X.; Nagase, S.; Akasaka, T.:Towards Relative Populations of Non/Isomeric Metallofullerenes: La@C76(Td) vs. La2@C76(CS, 17490) Fullerenes, Nanotubes and Carbon Nanostruct. 2014, 22, 299-306. DOI: 10.1080/1536383X.2013.863764
(60)Slanina, Z.*; Uhlik, F.; Lee, S.L.; Suzuki, M.; Lu, X.; Mizorogi, N.; Nagase, S.; Akasaka, T.:Calculated Temperature Development of the Relative Stabilities of Yb@C82 Isomers Fullerenes, Nanotubes, Carbon Nanostruct. 2014, 22, 147-154. DOI: 10.1080/1536383X.2013.794345
(59)Slanina, Z.*; Uhlik, F.; Lee, S.L.; Adamowicz, L.; Kurihara, H.; Nikawa, H.; Lu, X.; Yamada, M.; Nagase, S.; Akasaka, T.:Computations on Metallofullerenes Derivatized during Extraction: La@ C80C6H3Cl2 and La@C-82-C6H3Cl2 Fullerenes, Nanotubes, Carbon Nanostruct. 2014, 22, 173-181. DOI: 10.1080/1536383X.2013.798724
(58)Ruan, J.; Xie, Y.; Cai, W.; Slanina, Z.; Mizorogi, N.; Nagase, S.; Akasaka, T.; Lu, X.*:Chemical Properties of Divalent Metallofullerenes Yb@D3h(1)C74 and Yb@C2(13)C84 Fullerenes, Nanotubes and Carbon Nanostructures, 2014, 22, 138-146. DOI: 10.1080/1536383X.2013.794344
(57) Olmstead, M.*; Zhang, J. Y.; Dorn, H.; Lu, X.; Popov, A.; Beavers, C.:Metal carbide clusters inside fullerene cages and the use of synchrotron radiation to reveal their structures. Abs. Papers Am. Chem. Soc. 2014, 247.
(56) Lu, X.*; Bao, L.; Akasaka, T.*; Nagase, S.:Recent progress in the chemistry of endohedral metallofullerenes Chem. Commun. 2014, 50, 14701-14715. DOI: 10.1039/C4CC05164E
(55)Liu, F.; Wei, T.; Wang, S.; Guan, J.; Lu, X.; Yang, S.*:A Bent Tb2C2 Cluster Encaged in a CS(6)/C82 Cage: Synthesis, Isolation and X- ray Crystallographic Study Fullerenes, Nanotubes, Carbon Nanostruct. 2014, 22, 215-226. DOI: 10.1080/1536383X.2013.801839
(54)Liu, B.; Cong, H.; Li, X.*; Yu, B.; Bao, L.; Cai, W.; Xie, Y.; Lu, X.*:Highly regioselective 1,3/dipolar cycloaddition of diphenylnitrilimine to Sc3N@IhC80 affording a very stable, unprecedented pyrazole/ring fused derivative of endohedral metallofullerenes Chem. Commun. 2014, 50, 12710-12713. DOI: 10.1039/c4cc06134a
(53)Li, M.*; Liu, Z.; Ruan, J.; Chen, X.; Xu, F.; Chen, X.; Lu, X.; Yang, S.*:Noncovalently grafting sulfonic acid onto graphene oxide for improved hole transport in polymer solar cells RSC Adv. 2014, 4, 53999-54006. DOI: 10.1039/C4RA11305E
(52)Fang, H.; Cong, H.; Suzuki, M.; Bao, L.; Yu, B.; Xie, Y.; Mizorogi, N.; Olmstead, M. M.*; Balch, A. L.*; Nagase, S.; Akasaka, T.*; Lu, X.*:Regioselective Benzyl Radical Addition to an Open-Shell Cluster Metallofullerene. Crystallographic Studies of Cocrystallized Sc3C2@Ih-C80 and Its SinglyBonded Derivative J. Am. Chem. Soc. 2014, 136, 10534-40. DOI: 10.1021/ja505858y
2013
(51)Zhang, W.; Suzuki, M.; Xie, Y.; Bao, L.; Cai, W.; Slanina, Z.; Nagase, S.; Xu, M.*; Akasaka, T.*; Lu, X.*:Molecular structure and chemical property of a divalent metallofullerene Yb@C2(13)C84 J. Am. Chem. Soc. 2013, 135, 12730-5. DOI: 10.1021/ja405223t
(50)Yang, S.*; Chen, C.; Liu, F.; Xie, Y.; Li, F.; Jiao, M.; Suzuki, M.; Wei, T.; Wang, S.; Chen, Z.*; Lu, X.*; Akasaka, T.*:An Improbable Monometallic Cluster Entrapped in a Popular Fullerene Cage: YCN@Cs(6)C82 Scientific Reports, 2013, 3, 1487. DOI: 10.1038/srep01487
(49)Xie, Y.; Lu, X.*; Akasaka, T.*; Nagase, S.:New features in coordination chemistry: Valuable hints from X-ray analyses of endohedral metallofullerenes Polyhedron 2013, 52, 3-9. DOI:10.1016/j.poly.2012.06.072
(48)Xie, Y. P.; Suzuki, M.; Cai, W.; Mizorogi, N.; Nagase, S.; Akasaka, T.*; Lu, X.*:Highly Regioselective Addition of Adamantylidene Carbene to Yb@C2v(3)C80 to Afford the First Derivative of Divalent Metallofullerenes Angew. Chem. Int. Ed. 2013, 52, 5142-5145. DOI: 10.1002/anie.201210164
(47)Suzuki, M.; Mizorogi, N.; Yang, T.; Uhlik, F.; Slanina, Z.; Zhao, X.; Yamada, M.; Maeda, Y.; Hasegawa, T.; Nagase, S.*; Lu, X.*; Akasaka, T.*:La2@Cs(17490)C76: A New Non/IPR Dimetallic Metallofullerene Featuring Unexpectedly Weak Metal/Pentalene Interactions Chem. Eur. J. 2013, 19,17125-17130. DOI: 10.1002/chem.201302821
(46)Lu, X.*; Akasaka, T.*; Nagase, S.:Carbide Cluster Metallofullerenes: Structure, Properties, and Possible Origin Acc. Chem. Res., 2013, 46, 1627-1635. DOI: 10.1021/ar4000086
(45)Feng, L.*; Suzuki, M.; Mizorogi, N.; Lu, X.; Yamada, M.; Akasaka, T.*; Nagase, S.*:Mapping the metal positions inside spherical C80 cages: Crystallographic and theoretical studies of Ce2@D5h-C80 and Ce2@Ih-C80 Chem. Eur. J. 2013, 19, 988-993. DOI: 10.1002/chem.201202341
(44)Cong, H.; Yu, B.; Akasaka, T.; Lu, X.*:Endohedral metallofullerenes: an unconventional core/shell coordination union Coord. Chem. Rev. 2013, 257, 2880-2898. DOI: 10.1016/j.ccr.2013.05.020
2012
(43)Suzuki, M.; Slanina, Z.; Mizorogi, N.; Lu, X.*; Nagase, S.*; Olmstead, M. M.*; Balch, A. L.*; Akasaka, T.*:Single-Crystal X-ray Diffraction Study of Three Yb@C82 Isomers Cocrystallized with NiII(octaethylporphyrin) J. Am. Chem. Soc. 2012, 134, 18772-18778. DOI: 10.1021/ja308706d
(42)Suzuki, M.; Lu, X.; Sato, S.; Nikawa, H.; Mizorogi, N.; Slanina, Z.; Tsuchiya, T.; Nagase, S.*; Akasaka, T.*:Where Does the Metal Cation Stay in Gd@C(2v(9)-C(82)? A Single-Crystal X-ray Diffraction Study Inorg. Chem. 2012, 51, 5270-5273. DOI: 10.1021/ic300186y
(41)Lu, X.; Nakajima, K.; Iiduka, Y.; Nikawa, H.; Tsuchiya, T.; Mizorogi, N.; Slanina, Z.; Nagase, S.*; Akasaka, T.*:The long-believed Sc2@C2v(17)-C84 is actually Sc2C2@C2v(9)-C82: unambiguous structure assignment and chemical functionalization Angew. Chem. Int. Ed. 2012, 51, 5889-5892. DOI: 10.1002/anie.201201325
(40)Lu, X.*; Feng, L.; Akasaka, T.*; Nagase, S.*:Current status and future developments of endohedral metallofullerenes Chem. Soc. Rev. 2012, 41, 7723-7760. DOI: 10.1039/C2CS35214A
(39)Lu, X.; Akasaka, T*.; Nagase, S*.:Soluble and Tubular Higher Fullerenes that Encapsulate Metals Angew. Chem. Int. Ed. 2012, 51, 2812-2814. DOI: 10.1002/anie.201108401
(38)Kurihara, H.; Lu, X.; Iiduka, Y.; Nikawa, H.; Mizorogi, N.; Slanina, Z.; Tsuchiya, T.; Nagase, S.*; Akasaka, T.*:Chemical Understanding of Carbide Cluster Metallofullerenes: A Case Study on Sc2C2@C2v(5)−C80 with Complete X-ray Crystallographic Characterizations J. Am. Chem. Soc. 2012, 134, 3139-3144. DOI: 10.1021/ja210101f
(37)Kurihara, H.; Lu, X.; Iiduka, Y.; Nikawa, H.; Hachiya, M.; Mizorogi, N.; Slanina, Z.; Tsuchiya, T.; Nagase, S.*; Akasaka, T.*:X-ray structures of Sc2C2@C2n(n = 40/42): in/depth understanding of the core/shell interplay in carbide cluster metallofullerenes Inorg. Chem. 2012, 51, 746-750. DOI:10.1021/ic202438u
(36)Kurihara, H.; Lu, X.; Iiduka, Y.; Mizorogi, N.; Slanina, Z.; Tsuchiya, T.; Nagase, S.; Akasaka, T.*:Sc2@C3v(8)C82 vs. Sc2C2@C3v(8)C82: drastic effect of C2 capture on the redox poperties of scandium metallofullerenes Chem. Commun. 2012, 1290-1292. DOI: 10.1039/c2cc16422a
(35)Hachiya, M.; Nikawa, H.; Mizorogi, N.; Tsuchiya, T.; Lu, X.*; Akasaka, T.*:Exceptional chemical properties of Sc@C2v(9)C82 probed with adamantylidene carbene J. Am. Chem. Soc. 2012, 134, 15550-15555. DOI: 10.1021/ja306890x
(34)Akasaka, T.*; Lu, X.:Structural and electronic properties of endohedral metallofullerenes The Chem. Rec. 2012, 12, 256-269. DOI: 10.1002/tcr.201100038
2011
(33)Yutaka Maeda,* Takahiro Tsuchiya, Xing Lu, Yuta Takano, Takeshi Akasaka* and Shigeru Nagase:Current progress on the chemical functionalization and supramolecular chemistry of M@C82 Nanoscale, 2011, 3, 2421-2429. DOI:10.1039/C0NR00968G
(32)Lu, X.; Nikawa, H.; Kikuchi, K.; Mizorogi, N.; Slanina, Z.; Tsuchiya, T.; Akasaka, T.*; Nagase, S.*:Radical Derivatives of Insoluble La@C74 : X/ray Structures, Metal Positions, and Isomerization Angew. Chem. Int. Ed. 2011, 50, 6356-6359.
(31)Lu, X.; Nakajima, K.; Iiduka, Y.; Nikawa, H.; Mizorogi, N.; Slanina, Z.; Tsuchiya, T.; Nagase, S.*; Akasaka, T.*:Structural elucidation and regioselective functionalization of an unexplored carbide cluster metallofullerene Sc2C2@Cs(6)-C82 J. Am. Chem. Soc. 2011, 133, 19553-19558.
(30)Lu, X.*; Lian, Y.; Nikawa, H.; Mizorogi, N.; Slanina, Z.; Akasaka, T.; Nagase, S.:The Role That Internal Metals Play in Endohedral Metallofullerenes In Fullerenes, Nanotubes, and Carbon Nanostructures - 219th Ecs Meeting; Guldi, D., Ed., 2011, 35, 105-111.
(29)Lu, X.; Lian, Y.; Beavers, C. M.; Mizorogi, N.; Slanina, Z.; Nagase, S.*; Akasaka, T.*:Crystallographic X/ray analyses of Yb@C2v(3)C80 reveal a feasible rule that governs the location of a rare earth metal inside a medium-sized fullerene J. Am. Chem. Soc. 2011, 133, 10772-10775.
(28)Lu, X.*; Akasaka, T.*; Nagase, S. *:Chemistry of endohedral metallofullerenes: the role of metals Chem. Commun. 2011, 47, 5942-5957.
(27)Kurihara, H.; Lu, X.; Iiduka, Y.; Mizorogi, N.; Slanina, Z.; Tsuchiya, T.; Akasaka, T. *; Nagase, S. *:Sc2C2@C80 rather than Sc2@C82: templated formation of unexpected C2v(5)-C80 and temperature-dependent dynamic motion of internal Sc2C2 cluster J. Am. Chem. Soc. 2011, 133, 2382-2385.
Before 2011
(26)Lu, X.; Slanina, Z.; Akasaka, T.*; Tsuchiya, T.; Mizorogi, N.; Nagase, S.*:Yb@C/2n (n=40, 41, 42): New Fullerene Allotropes with Unexplored Electrochemical Properties J. Am. Chem. Soc. 2010, 132, 5896-5905.
(25)Lu, X.; Nikawa, H.; Tsuchiya, T.; Akasaka, T.*; Toki, M.; Sawa, H.; Mizorogi, N.; Nagase, S.*:Nitrated Benzyne Derivatives of La@C82: Addition of NO2 and Its Positional Directing Effect on the Subsequent Addition of Benzynes Angew. Chem. Int. Ed. 2010, 49, 594-597.
(24)Akasaka, T.*; Lu, X.; Kuga, H.; Nikawa, H.; Mizorogi, N.; Slanina, Z.; Tsuchiya, T.; Yoza, K.; Nagase, S.*:Dichlorophenyl Derivatives of La@C3v(7)C82: Endohedral Metal Induced Localization of Pyramidalization and Spin on a Triple/Hexagon Junction Angew. Chem. Int. Ed. 2010, 49, 9715-9719.
(23)Lu, X.; Nikawa, H.; Feng, L.; Tsuchiya, T.; Maeda, Y.; Akasaka, T.*; Mizorogi, N.; Slanina, Z.; Nagase, S.*:Location of the yttrium atom in Y@C82 and its influence on the reactivity of cage carbons J. Am. Chem. Soc. 2009, 131, 12066-12067.
(22)Lu, X.; Nikawa, H.; Tsuchiya, T.; Maeda, Y.; Ishitsuka, M. O.; Akasaka, T.*; Toki, M.; Sawa, H.; Slanina, Z.; Mizorogi, N.; Nagase, S.*:Bis/Carbene Adducts of Non/IPR La2@C72: Localization of High Reactivity around Fused Pentagons and Electrochemical Properties Angew. Chem. Int. Ed. 2008, 47, 8642-8645.
(21)Lu, X.; Nikawa, H.; Nakahodo, T.; Tsuchiya, T.; Ishitsuka, M. O.; Maeda, Y.; Akasaka, T.*; Toki, M.; Sawa, H.; Slanina, Z.; Mizorogi, N.; Nagase, S.*:Chemical understanding of a non/IPR metallofullerene: Stabilization of encaged metals on fused/pentagon bonds in La2@C72 J. Am. Chem. Soc., 2008, 130, 9129-9136.
(20)Lu, X.; Imae, T.*:Size/controlled in situ synthesis of metal nanoparticles on dendrimer/modified carbon nanotubes J. Phys. Chem. C 2007, 111, 2416-2420.
(19)Lu, X.; Imae, T.*:Dendrimer-mediated synthesis of water-dispersible carbon-nanotube supported oxide nanoparticles J. Phys. Chem. C 2007, 111, 8459-8462.
(18)Zhang, H. Y.; Wang, J. P.; Lu, X.; Yang, K. Y.; Niu, C. J.*:Effect of praseodymium(III) on zinc(II) species in human interstitial fluid Biological Trace Element Research 2005, 107, 101-111.
(17)Lu, X.; Shi, Z. J.; Sun, B. Y.; He, X. R.; Gu, Z. N.*:Isolation and spectroscopic study of a series of monogadolinium endohedral metallofullerenes Fullerenes, Nanotubes, Carbon Nanostruct. 2005, 13, 13-20.
(16)Lu, X.; Li, H. J.; Sun, B. Y.; Shi, Z. J.; Gu, Z. N.*:Selective reduction and extraction of Gd@C-82 and Gd-2@C80 from soot and the chemical reaction of their anions Carbon 2005, 43, 1546-1549.
(15)Zhang, H. Y.; Lu, X.; Wang, J. P.; Yang, K. Y.; Niu, C. J.*; Ni, J. Z.:Computer simulation of Pr(III) speciation in human interstitial fluid Chemical Speciation and Bioavailability 2004, 16, 153-158.
(14)Xu, J. X.; Lu, X.; Zhou, X. H.; He, X. R.; Shi, Z. J.*; Gu, Z. N.:Synthesis, isolation, and spectroscopic characterization of ytterbium·containing metallofullerenes Chem. Mater. 2004, 16, 2959-2964.
(13)Lu, X.; Zhou, X. H.; Shi, Z. J.; Gu, Z. N.*:Nucleophilic addition of glycine esters to Gd@C82 Inorg. Chim. Acta 2004, 357, 2397-2400.
(12)Lu, X.; Xu, J. X.; Shi, Z. J.; Sun, B. Y.; Gu, Z. N.; Liu, H. D.; Han, H. B.:Studies on the relaxivities of novel MRI contrast agents two water.soluble derivatives of Gd@C82 Chem. J. Chin. Univ. 2004, 25, 697-700.
(11)Lu, X.; Xu, J. X.; He, X. R.; Shi, Z. J.; Gu, Z. N.*:Addition of benzyne to Gd@C82 Chem. Mater. 2004, 16, 953-955.
(10)Lu, X.; He, X. R.; Feng, L.; Shi, Z. J.; Gu, Z. N.*:Synthesis of pyrrolidine ring/fused metallofullerene derivatives Tetrahedron 2004, 60, 3713-3716.
(9)Feng, L.; Lu, X.; He, X. R.; Shi, Z. J.; Gu, Z. N.*:Reactions of endohedral metallofullerenes with azomethine ylides: an efficient route toward metallofullerene pyrrolidines Inorg. Chem. Commun. 2004, 7, 1010-1013.
(8)Zhang, H. Y.; Lu, X.; Wang, J. P.; Yang, K. Y.; Niu, C. J.*; Ni, J. Z.:Computer simulation for effect of Pr(III) on Ca(II) speciation in human interstitial fluid Biological Trace Element Research 2003, 95, 39-48.
(7)Zhang, H. Y.; Lu, X.; Wang, J. P.; Yang, K. Y.; Niu, C. J.*:Computer simulation for effect of Pr(III) on Ca(II) speciation in human interstitial fluid Biological Trace Element Research 2003, 94, 131-140.
(6)Zhang, H. Y.; Lu, X.; Niu, C. J.*; Ni, J. Z.:Computer simulation of insoluble Pr(III) speciation in human interstitial fluid Chin. Chem. Lett. 2002,13, 658-659.
(5)Lu, X.; Wang, Y.; Zhang, H. Y.; Wang, J. P.; Niu, C. J. *; Ni, J. Z.:Computer simulation for effect of Tb3+ on Ca2+ speciation in human plasma J. Rare Earths 2002, 20, 238-240.
(4)Wang, Y.; Lu, X.; Zhang, H. Y.; Yang, K. Y.; Niu, C. J.*; Ni, J. Z.:Studies on insoluble species of Gd (III) in human blood plasma by computer simulation Chem. Res. Chin. Uni. 2001, 17, 352-355.
(3)Wang, Y.; Lu, X.; Wang, S. Y.; Han, J. F.; Yang, K. Y.; Niu, C. J.*; Ni, J. Z.:Study on effect of Gd (III) speciation on Ca (II) speciation in human blood plasma by computer simulation Chin. Chem. Lett. 2001, 12, 161-162.
(2)Lu, X.; Wang, Y.; Zhang, H. Y.; Niu, C. J.*; Ni, J. Z.:Tb(III) speciation in human blood plasma by computer simulation Chin. Chem. Lett. 2001, 12, 809-812.
(1)Wang, Y.; Han, J. F.; Lu, X.; Yang, K. Y.; Niu, C. J.; Ni, J. Z.:Species of rare earth (III), calcium (II) and zinc (II) in the presence of L/histidine and L/typtophane Chin. J. of Anal. Chem. 2000, 28, 1118-1120.
